Thermochemical Investigation on Organic Sulfur Compounds. IV. Thermochemical Sulfur Bond Energy Terms.
نویسندگان
چکیده
منابع مشابه
A kinetic and thermochemical database for organic sulfur and oxygen compounds.
Potential energy surfaces and reaction kinetics were calculated for 40 reactions involving sulfur and oxygen. This includes 11 H2O addition, 8 H2S addition, 11 hydrogen abstraction, 7 beta scission, and 3 elementary tautomerization reactions, which are potentially relevant in the combustion and desulfurization of sulfur compounds found in various fuel sources. Geometry optimizations and frequen...
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(34)S enrichment is shown to occur during sulfurization reactions and for the first time conclusively attributed to an isotope equilibrium effect rather than selective addition of (34)S enriched nucleophiles.
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The inability of the methionine requiring Escherichia coli mutant (1-344) to grow in methionine free media containing inorganic sulfur, cystine, or homocystine has been demonstrated (Lampen et al., 1947). While methionine has been shown to be essential for growth, the metabolism of nonmethionine sulfur added to media containing methionine has not been investigated directly. In the results repor...
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(tetrahydrofuran) at 703C for 16 h. The ester residue is then converted to a 6,6-dideuteriohexose residue, the O-methyl ethers of which are easily distinguishable by GC-MS of the derived alditol acetates. An alternative to acid hydrolysis that is applicable to most polysaccharides and glycoconjugates, including those containing acid-labile residues or glycosidic linkages resistant to hydrolysis...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1955
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.09-0837